You can create your own toolbars in fckconfig.js which is found here:
/providers/htmleditorproviders/FCK/Custom/fckconfig.js
You already have:
FCKConfig.ToolbarSets["Default"] = [
['Source','DocProps','-','Save','NewPage','Preview','-','Templates'],
['Cut','Copy','Paste','PasteText','PasteWord','-','Print','SpellCheck'],
['Undo','Redo','-','Find','Replace','-','SelectAll','Removeformat'],
['form','Checkbox','Radio','TextField','Textarea','Select','Button','ImageButton','HiddenField'],
'/',
['Bold','Italic','Underline','StrikeThrough','-','Subscript','Superscript'],
['OrderedList','UnorderedList','-','Outdent','Indent'],
['JustifyLeft','JustifyCenter','JustifyRight','JustifyFull'],
['Link','Unlink','Anchor'],
['Image','Flash','Table','Rule','Smiley','SpecialChar','PageBreak'],
'/',
['Style','Fontformat','FontName','FontSize'],
['TextColor','BGColor'],
['FitWindow','-','About']
] ;
FCKConfig.ToolbarSets["DNNDefault"] = [
['Source','Preview','-','Templates'],
['Cut','Copy','Paste','PasteText','PasteWord','-','Print','SpellCheck'],
['Undo','Redo','-','Find','Replace','-','SelectAll','Removeformat'],
['Bold','Italic','Underline','StrikeThrough','-','Subscript','Superscript'],
['OrderedList','UnorderedList','-','Outdent','Indent'],
['JustifyLeft','JustifyCenter','JustifyRight','JustifyFull'],
['Link','Unlink','Anchor'],
['Image','Flash','Table','Rule','Smiley','SpecialChar','PageBreak'],
['Style','Fontformat'],['FontName','FontSize'],
['TextColor','BGColor'],
['FitWindow','-','About']
] ;
FCKConfig.ToolbarSets["NoGallery"] = [
['Source','Preview','-','Templates'],
['Cut','Copy','Paste','PasteText','PasteWord','-','Print','SpellCheck'],
['Undo','Redo','-','Find','Replace','-','SelectAll','Removeformat'],
['Bold','Italic','Underline','StrikeThrough','-','Subscript','Superscript'],
['OrderedList','UnorderedList','-','Outdent','Indent'],
['JustifyLeft','JustifyCenter','JustifyRight','JustifyFull'],
['Link','Unlink','Anchor'],
['Table','Rule','Smiley','SpecialChar','PageBreak'],
['Style','Fontformat'],['FontName','FontSize'],
['TextColor','BGColor'],
['FitWindow','-','About']
] ;
FCKConfig.ToolbarSets["Basic"] = [
['Bold','Italic','-','OrderedList','UnorderedList','-','Link','Unlink','-','About']
] ;
And you can create your own the same way....